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Hierarchically-Porous Polymers with Fast Absorption
KAIST's Professor Myungeun Seo and his research team from the Graduate School of Nanoscience and Technology has developed a method to form micropores of less than 2 nanometers within porous polymers where 10 nanometers long mesopores connect like a net. The advantage of the porous polymers is fast absorption of molecules.
Porous polymers with micropores of less than 2 nanometers, like a zeolite, have a large surface area. They are used as a means to store hydrogen-based molecules or as a catalytic support that can be used as a surface to convert a material into a desired form. However, because the size of the pores in its path was too small for the molecules, it took a long time to spread into the pores and reach the surface.
To reach the surface efficiently, a lung cell or the vein of a leaf has a structure wherein the pores are subdivided into different sizes so that the molecule can spread throughout the organ. A technology that can create not only micropores but also bigger pores was necessary in order to create such structure.
The research team solved the issue by implementing a "self-assembly" of block polymers to easily form a net-like nanostructure from mesopores of 10 nanometers.
The team created hierarchically-porous polymers consisting of two different types of pores by using a hypercrosslinking reaction along with the "self-assembly" method. The reaction creates micropores within the chain after the polymer chain is confined by a chemical bond.
This porous polymer has micropores that are smaller than 2 nanometers on the walls of mesopores while 10 nanometers long mesopores forming 3-dimensional net structures. Because of the "self-assembly" method, the size of mesopores can be adjusted within the range of 6 to 15 nanometers.
This is the first case where a porous polymer has both well-defined mesopores and micropores. The research team verified the effect of hierarchically-porous structures on absorption of molecules by confirming that the porous polymer had faster absorption speeds than a polymer consisting only of micropores.
Professor Seo said, “The study has found a simple way to create different sizes of pores within a polymer.” He expected that the hierarchically-porous polymers can be used as a catalytic support in which fast diffusion of molecules is essential, or for molecule collection.
The research was sponsored by National Research Foundation of Korea and published online in the Journal of the American Chemical Society.
Figure 1 – Net-like Structure of Hierarchically-Porous Polymers with Mesopores and Micropores on the walls of Mesopores.
Figure 2 - Hierarchically-Porous Polymers
Figure 3 – Comparison of Porous-Polymers consisting of Mesopores only (left), and Mesopores and Micropores (right)
2015.01.13 View 9962 -
Broadband and Ultrathin Polarization Manipulators Developed
Professor Bumki Min from the Department of Mechanical Engineering at KAIST has developed a technology that can manipulate a polarized light in broadband operation with the use of a metamaterial.
It is expected that this technology will lead to the development of broadband optical devices that can be applied to broadband communication and display.
When an object or its structure is analyzed by using a polarized light such as a laser, the results are generally affected by the polarized state of the light. Therefore, in an optics laboratory, the light is polarized by various methods.
In such cases, researchers employ wave plates or photoactive materials. However, the performance of these devices depend vastly on wavelength, and so they are not suitable to be used as a polarizer, especially in broadband.
There were many attempts to make artificial materials that are very photoactive by using metamaterials which have a strong resonance. Nonetheless, because the materials had an unavoidable dispersion in the resonance frequency, they were not adequate for broadband operation.
Professor Min’s research team arranged and connected helical metamaterials that are smaller than the wavelength of light. They verified theoretically and experimentally that polarized light can be constantly rotated regardless of the wavelength by super-thin materials that have thickness less than one-tenth of the wavelength of the light. The experiment which confirmed the theory was conducted in the microwave band.
Broadband polarized rotational 3D metamaterials were found to rotate the polarized microwave within the range of 0.1 GHz to 40 GHz by 45 degrees regardless of its frequency. This nondispersive property is quite unnatural because it is difficult to find a material that does not change in a wide band.
In addition, the research team materialized the broadband nondispersive polarized rotational property by designing the metamaterial in a way that it has chirality, which determines the number of rotations proportional to the wavelength.
Professor Min said, “As the technology is able to manipulate ultrathin polarization of light in broadband, it will lead to the creation of ultra-shallow broadband optical devices.”
Sponsored by the Ministry of Science, ICT and Future Planning of the Republic of Korea and the National Research Foundation of Korea, this research was led by a PhD candidate, Hyun-Sung Park, under the guidance of Professor Min. The research findings were published online in the November 17th issue of Nature Communications.
Figure 1 – Broadband and Ultrathin Polarization Manipulators Produced by 3D Printer
Figure 2 – Concept of Broadband and Ultrathin Polarization Manipulators
2014.12.03 View 13497 -
KAIST Robotic Art: Exhibit called "Artificial Brain, Robots Evolve"
It is not difficult to find the desire to create a Neoanthropinae in the history of mankind. Humans evolve through man-made extensions and live by self-training them. This is Seung Hyun Son’s description which encourages us to discuss the changes man-made humanoids would bring to our future lives. He depicts this in “Theory of Evolution: From mankind to humanoid” in the “Artificial Brain, Robots Evolve” exhibition in the KI Building, KAIST, from 21 November 2014 to 8 February 2015.
KAIST's Art and Design Committee (led by President Myung Seok Kim) is holding the third experimental art exhibition based on the integration of science and art. The previous exhibition themes were “See the Sky” in 2012 and “Life is Beautiful” in 2013. The exhibition is divided into five subtopics: Move, Feel, Think, Express, and Experiment in Imagination.
The exhibits are by 17 artists including Nam June Paik, Nancy Lang, and KAIST Professor Myung Seok Kim. The main exhibits include “Cloud Face,” by Seung Baek Shin and Yong Hoon Kim, that shows up as error on computer but can be seen by human eyes and “Brains in Vat," by Boo Rok Lee and Myung Chul Kim based on KAIST's robotic lab’s materials and motif. Also, “The May of My Life” by Professor Myung Seok Kim’s lab reminds us of the relationship between robot and human.
President Myung Seok Kim said, “The range of content in cultural art will inspire students’ imagination.” He continued, “I hope this exhibition will awaken both scientific ideas and artistic sense.”
The opening ceremony of the exhibition will be held from 14:00, 21 November. The “Artificial Brain, Robots Evolve” exhibition is hosted by the Daejeon Museum of Art and sponsored by National Museum of Modern and Contemporary Art and Soma Museum.
Pictures from top to bottom are Cloud Face, Brains in Vat, The May of My Life_1, and The May of My Life_2.
2014.11.21 View 9115 -
President Steve Kang will serve as the Chairman of Global Agenda Council on the Future of Electronics of the World Economic Forum
President Steve Kang of KAIST has been appointed to the Chairman of the Global Agenda Council (GAC) on the Future of Electronics of the World Economic Forum (WEF). He will serve the position for two years until September 2016.
President Kang and WEF council members co-hosted, with the government of the United Arab Emirates (UAE), the Future Circles Initiative, a future-focused, innovative brainstorming conference to help find strategies and ideas for the development of UAE. The conference took place on November 11-12, 2014 at the Mina Al Salam Hotel in Dubai.
WEF has about 80 GACs. Each council consists of 15 experts and thought leaders from the academia, industry, government, business, and non-profit sector and deals with specific issues that are important and relevant to the global community such as ageing, artificial intelligence and robotics, brain research, food and nutrition security, education, social media, and future of chemicals, advanced materials and biotechnology.
President Kang was recognized for his contribution to the advancement of science and higher education as an engineer, scholar, and professor. He led the development of the world’s premier CMOS 32-bit microprocessors while working at the AT&T Bell Laboratories. He also taught and conducted research at the University of California, Santa Cruz, and the University of Illinois, Urbana-Champaign. President Kang served as the chancellor of the University of California at Merced from March 2007 to June 2011.
2014.11.11 View 10921 -
KAIST and ETH Zürich Sign a MOU on Cooperation in Education and Research
KAIST and ETH Zürich, a leading engineering, science, and technology university in Switzerland, signed a memorandum of understanding (MOU) to cooperate in engineering education and research on November 3, 2014 at the KAIST campus.
The two universities have agreed to implement student and academic exchange programs, collaborate on research in the advanced fields of engineering, and host joint conferences and seminars.
President Steve Kang of KAIST (on the right in the picture below) and President Ralph Eichler of ETH Zürich (on the left) attended the signing ceremony.
President Kang commented that KAIST and ETH Zürich would mutually benefit from the cooperation, sharing their knowledge and resources to further develop their faculty and student's work in the field.
2014.11.11 View 7220 -
KAIST and the National Assembly of Korea Create a Committee to Plan "Patent Hub Korea"
The KAIST Graduate School of Future Strategy (GSFS) and the National Assembly of the Republic of Korea held a meeting at the National Assembly building in Seoul on September 23, 2014.
At the meeting, the two organizations agreed to create a planning committee that will work for the construction of Korea as a global patent hub. In addition, the two also reviewed national laws and regulations related to patents and intellectual property rights (IPR) and discussed a future action agenda.
Dean Kwang-Hyung Lee of GSFS, Chairman Ui-Hwa Chung of the National Assembly, Chairman Jong-Yong Yoon of the Presidential Council on Intellectual Property, and many representatives from the academia, government, and law participated in the meeting.
Dean Lee, who is the co-chairman of the planning committee, said:
“Although Korea has globally ranked number five in patents and IPR, it still suffers from the lack of relevant legal systems and professionals. I hope that the planning committee will serve as a catalyst to make Korea stronger in the field of intellectual property and to accelerate the creation of the Patent Hub Korea.”
2014.09.24 View 9070 -
PIBOT, a small humanoid robot flies an aircraft
The 2014 IEEE/RSJ International Conference on Intelligent Robots and Systems (IROS 2014) took place in Chicago, Illinois, on September 14-18, 2014.
Professor David Hyunchul Shim and his students from the Department of Aerospace Engineering, KAIST, presented a research paper entitled “A Robot-machine Interface for Full-functionality Automation Using a Humanoid” at the conference.
The robot called “PIBOT,” a pint-sized, tiny humanoid robot, uses a mixture of flight data and visuals to fly an airplane, capable of identifying and operating all of the buttons and switches in the cockpit of a normal light aircraft designed for humans.
For now, the robot is only flying a simulator, but Professor Shim expects that “PIBOT will help us have a fully automated flight experience, eventually replacing human pilots.”
The IEEE Spectrum magazine published an article on PIBOT posted online September 18, 2014. Please follow the link below for the article:
IEEE Spectrum, September 18, 2014
Tiny Humanoid Robot Learning to Fly Real Airplanes
http://spectrum.ieee.org/automaton/robotics/humanoids/tiny-humanoid-robot-learning-to-fly-real-airplanes
2014.09.23 View 15653 -
EureCar, KAIST's Self-Driving Car, Made It to the Global Student Design Finalists at the 2014 National Instruments Annual Conference in Austin, Texas
The National Instruments Week 2014, an annual conference hosted by the National Instruments Corporation (NI), a global producer of automated test equipment and virtual instrumentation software, was held on August 4-7, 2014 at the Austin Convention Center in Texas. This international conference on graphical system design brought together more than 3,200 leading engineers and scientists across a spectrum of industries, from automotive to telecommunications, to robotics to energy.
On the third day of the keynote sessions at the conference, August 7, 2014, the winner of the Global Student Design Competition (GSDC) was announced.
EureCar, a self-driving car developed by Professor “David” Hyunchul Shim at the Department of Aerospace Engineering, KAIST, and his students, was one of the three finalists that were invited to the conference to contend for the Global Grand Prize.
The three finalists, each selected from a regional competition, were: EureCar from KAIST, Sepios, a nautical robot from Swiss Federal Institute of Technology in Zürich (ETH Zürich), and NASA Student Launch Project from the University of North Carolina at Charlotte. A total of 3,250 student research teams from 25 countries entered the 2014 GSDC, and the winner was ETH Zürich.
GSDC is designed to promote a better understanding and application by engineering students of NI’s system design software and hardware in their research and learning. Participating students utilized NI’s LabVIEW (software) and CompactRIO (hardware) to create their own solutions to engineering problems that encompass inexpensive medical devices to complex underwater autonomous vehicles.
For details about the finalists, please go to:
http://www.kaist.ac.kr/Upl/downfile/TS4159_Wahby_Student_Design_Showcase.pdf
2014.08.18 View 10229 -
KAIST Researchers Develops Sensor That Reads Emotional States of Users
A piloerection monitoring sensor attached on the skin
The American Institute of Physics distributed a press release dated June 24, 2014 on a research paper written by a KAIST research team, which was published in its journal entitled Applied Physics Letters (APL). APL features concise, up-to-date reports in significant new findings in applied physics.
According to the release, “KAIST researchers have developed a flexible, wearable 20 mm x 20 mm polymer sensor that can directly measure the degree and occurrence on the skin of goose bumps, which is caused by sudden changes in body temperature or emotional states.”
The lead researcher was Professor Young-Ho Cho from the Department of Bio and Brain Engineering at KAIST.
If you would like to read the press release, please go to the link below:
American Institute of Physics, June 24, 2014
“New technology: The goose bump sensor”
http://www.eurekalert.org/pub_releases/2014-06/aiop-ntt062314.php
2014.06.26 View 9544 -
Thermoelectric generator on glass fabric for wearable electronic devices
Wearable computers or devices have been hailed as the next generation of mobile electronic gadgets, from smart watches to smart glasses to smart pacemakers. For electronics to be worn by a user, they must be light, flexible, and equipped with a power source, which could be a portable, long-lasting battery or no battery at all but a generator. How to supply power in a stable and reliable manner is one of the most critical issues to commercialize wearable devices.
A team of KAIST researchers headed by Byung Jin Cho, a professor of electrical engineering, proposed a solution to this problem by developing a glass fabric-based thermoelectric (TE) generator that is extremely light and flexible and produces electricity from the heat of the human body. In fact, it is so flexible that the allowable bending radius of the generator is as low as 20 mm. There are no changes in performance even if the generator bends upward and downward for up to 120 cycles.
To date, two types of TE generators have been developed based either on organic or inorganic materials. The organic-based TE generators use polymers that are highly flexible and compatible with human skin, ideal for wearable electronics. The polymers, however, have a low power output. Inorganic-based TE generators produce a high electrical energy, but they are heavy, rigid, and bulky.
Professor Cho came up with a new concept and design technique to build a flexible TE generator that minimizes thermal energy loss but maximizes power output. His team synthesized liquid-like pastes of n-type (Bi2Te3) and p-type (Sb2Te3) TE materials and printed them onto a glass fabric by applying a screen printing technique. The pastes permeated through the meshes of the fabric and formed films of TE materials in a range of thickness of several hundreds of microns. As a result, hundreds of TE material dots (in combination of n and p types) were printed and well arranged on a specific area of the glass fabric.
Professor Cho explained that his TE generator has a self-sustaining structure, eliminating thick external substrates (usually made of ceramic or alumina) that hold inorganic TE materials. These substrates have taken away a great portion of thermal energy, a serious setback which causes low output power.
He also commented,
"For our case, the glass fabric itself serves as the upper and lower substrates of a TE generator, keeping the inorganic TE materials in between. This is quite a revolutionary approach to design a generator. In so doing, we were able to significantly reduce the weight of our generator (~0.13g/cm2), which is an essential element for wearable electronics."
When using KAIST's TE generator (with a size of 10 cm x 10 cm) for a wearable wristband device, it will produce around 40 mW electric power based on the temperature difference of 31 °F between human skin and the surrounding air.
Professor Cho further described about the merits of the new generator:
"Our technology presents an easy and simple way of fabricating an extremely flexible, light, and high-performance TE generator. We expect that this technology will find further applications in scale-up systems such as automobiles, factories, aircrafts, and vessels where we see abundant thermal energy being wasted."
This research result was published online in the March 14th issue of Energy & Environmental Science and was entitled "Wearable Thermoelectric Generator Fabricated on Glass Fabric."
Youtube Link: http://www.youtube.com/watch?v=BlN9lvEzCuw&feature=youtu.be
[Picture Captions]
Caption 1: The picture shows a high-performance wearable thermoelectric generator that is extremely flexible and light.
Caption 2: A thermoelectric generator developed as a wristband. The generator can be easily curved along with the shape of human body.
Caption 3: KAIST’s thermoelectric generator can be bent as many as 120 times, but it still shows the same high performance.
2014.04.21 View 21973 -
An Electron Cloud Distribution Observed by the Scanning Seebeck Microscope
All matters are made of small particles, namely atoms. An atom is composed of a heavy nucleus and cloud-like, extremely light electrons.
Korean researchers developed an electron microscopy technique that enables the accurate observation of an electron cloud distribution at room-temperature. The achievement is comparable to the invention of the quantum tunneling microscopy technique developed 33 years ago.
Professor Yong-Hyun Kim of the Graduate School of Nanoscience and Technology at KAIST and Dr. Ho-Gi Yeo of the Korea Research Institute of Standards and Science (KRISS) developed the Scanning Seebeck Microscope (SSM). The SSM renders clear images of atoms, as well as an electron cloud distribution. This was achieved by creating a voltage difference via a temperature gradient.
The development was introduced in the online edition of Physical Review Letters (April 2014), a prestigious journal published by the American Institute of Physics.
The SSM is expected to be economically competitive as it gives high resolution images at an atomic scale even for graphene and semiconductors, both at room temperature. In addition, if the SSM is applied to thermoelectric material research, it will contribute to the development of high-efficiency thermoelectric materials.
Through numerous hypotheses and experiments, scientists now believe that there exists an electron cloud surrounding a nucleus. IBM's Scanning Tunneling Microscope (STM) was the first to observe the electron cloud and has remained as the only technique to this day. The developers of IBM microscope, Dr. Gerd Binnig and Dr. Heinrich Rohrer, were awarded the 1986 Nobel Prize in Physics.
There still remains a downside to the STM technique, however: it required high precision and extreme low temperature and vibration. The application of voltage also affects the electron cloud, resulting in a distorted image.
The KAIST research team adopted a different approach by using the Seebeck effect which refers to the voltage generation due to a temperature gradient between two materials.
The team placed an observation sample (graphene) at room temperature (37~57℃) and detected its voltage generation. This technique made it possible to observe an electron cloud at room temperature.
Furthermore, the research team investigated the theoretical quantum mechanics behind the electron cloud using the observation gained through the Seebeck effect and also obtained by simulation capability to analyze the experimental results.
The research was a joint research project between KAIST Professor Yong-Hyun Kim and KRISS researcher Dr. Ho-Gi Yeo. Eui-Seop Lee, a Ph.D. candidate of KAIST, and KRISS researcher Dr. Sang-Hui Cho also participated. The Ministry of Science, ICT, and Future Planning, the Global Frontier Initiative, and the Disruptive Convergent Technology Development Initiative funded the project in Korea.
Picture 1: Schematic Diagram of the Scanning Seebeck Microscope (SSM)
Picture 2: Electron cloud distribution observed by SSM at room temperature
Picture 3: Professor Yong-Hyun Kim
2014.04.04 View 17317 -
Materials Developed for Sodium Rechargeable Battery by EEWS
The research group of Professor William Goddard III, You-Sung Jung, and Jang-Wook Choi from the Graduate School of Energy, Environment, Water, and Sustainability (EEWS) at KAIST has developed a new sodium-ion rechargeable battery which operates at a high voltage, can be charged, and stably discharges over 10,000 cycles. The research results were published in the online version of the Proceedings of the National Academy of Sciences of the United States of America (PNAS) on December 30, 2013.
Since the material costs of sodium rechargeable batteries is 30 to 40 times lower than lithium batteries, it has received attention as an energy saving tool for smart grids and as the next generation of lithium rechargeable batteries. Until now, sodium-ion rechargeable batteries have had issues with stability when charging and discharging. The research group developed a vanadium-based electrode to solve these problems.
The group said follow-up research will be continued to develop advanced technology on sodium rechargeable batteries as it is still currently in the beginning stages.
The research team: From left to right is Professors William Goddard, You-Sung Jung, and Jang-Wook Choi
2014.01.13 View 13108